山东金青顶金矿床和七宝山金矿床的流体包裹体REE组成   总被引：6，自引：0，他引：6  

陈绪松  徐九华  刘建明  谢玉玲  朱和平  李永兵 《矿床地质》2002,21(4):387-392

文章运用电感耦合等离子体质谱（ICP-MS）方法，研究了金青顶金矿床和七宝山金矿床的脉石英中流体包裹体REE组成特征，结果表明流体包裹体的REE均为LREE富集型，并显示Eu正异常。成矿流体REE配分模式和REE参数特征表明它们具有相当的来源。与金矿有关的成矿母岩，即昆嵛山花岗岩和七宝山次火山岩的REE特征也极为相似，反映成矿流体的REE组成都有从成岩向成矿过程演化继承的关系。矿床流体包裹体REE组成的相似特征及矿床碳氧同位素等特点表明，金青顶金矿床和七宝山金矿床是华北东部中生代同一构造热事件的产物。  相似文献   

成矿流体演化与成矿物理化学   总被引：7，自引：0，他引：7  

费红彩  肖荣阁 《矿物岩石地球化学通报》2002,21(2):139-144

成矿流体是富含挥发分 (CO2 、CH4等 )是具有较高含盐度的特殊地质流体。本文讨论了在流体演化过程中挥发分的来源 ,指出主要来自水岩作用、有机质分解及地幔去气和岩浆 ;碱金属及卤素同样具有多来源的性质 ,以海水、含盐系淋滤、建造水为主要来源 ,含盐系重熔可以形成富含碱金属的成矿流体。流体演化过程中氢氧同位素、硫同位素的分馏主要与温度、水岩比值或硫源丰度有关。一个重要的结论是 ,成矿流体的形成主要与地质作用有关 ,而流体来源是次要的。海底热水流体的地球化学特征以高δ3 4 S值、中稀土富集及正铕异常为特征。本文总结了热水流体成矿物理化学条件 ,指出水热流体物相点 :1) 10 80℃ ,7.5× 10 8Pa水溶液与硅酸岩熔浆分熔点 ;2 )水溶液的第二个临界点是气水溶液的超临界点 (374.15℃ ,2 .2 1× 10 7Pa) ;3)水溶液的沸点 (≥ 10 0℃ ,≥ 1× 10 5Pa) ;4)水溶液的冰点 (≤ 0℃ ,1× 10 5Pa) ;5 )H2 O CO2 体系的不混溶温度点 (2 6 6℃ ,2 .15×10 8Pa[1 3 ] 等是重要的成矿相变点。  相似文献   

吉林集安铅锌矿地球化学与分散元素   总被引：2，自引：0，他引：2  

张宝贵  张忠  胡静 《矿物学报》2002,22(1):62-66

吉林集安铅锌矿床是我国最早报导的少数几个典型低温铅锌矿床之一。矿化具有多期次特点 ,富矿体都是多期次矿化叠加的产物。根据矿化先后和矿物生成顺序将矿化分为五个阶段 :①石英 黄铁矿矿化阶段 ;②重晶石 闪锌矿矿化阶段 ;③石英 方铅矿矿化阶段 ;④石英 黄铁矿矿化阶段 ;⑤碳酸盐 氧化矿物矿化阶段。用均一法和爆裂法测得石英、重晶石、闪锌矿包裹体成矿温度变化在 1 1 0℃～ 1 97℃之间。矿床中除含铅锌矿外 ,还有微量的Pt和Pd,并普遍含分散元素Cd、Ga、Tl、In、Se、Ge、Te,其中以Cd含量最高 ,闪锌矿中Cd含量最高可达 71 5 5× 1 0 6。分散元素主要呈类质同象形式赋存在各种矿物之中 ,未发现独立矿物。通过矿床地质和硫铅同位素研究表明该铅锌矿床属低温沉积 改造型层控矿床。  相似文献   

湘中锡矿山锑矿床成矿物质来源的同位素示踪   总被引：14，自引：0，他引：14  

彭建堂  胡瑞忠  邹利群  刘建雄 《矿物学报》2002,22(2):155-159

本文利用放射成因同位素（Pb、Sr)和轻稳定同位素（C、O）对锡矿山超大型锑矿床的成矿物质来源进行了示踪，从物源角度揭示了其在规模成矿、元素发生超常富集的原因。研究表明，锡矿山锑矿床的成矿物质不可能是来自赋矿围岩；深部地幔和基底都卷入了该矿的成矿作用；富Sb的交代型地幔和富Sb的元古界基底为其大规模成矿提供了充足的矿源，两者是形成锡成山超大型锑矿床的前提条件。  相似文献   

Gold Occurrence and Ore Genesis,Yata Micro—Disseminated Gold Deposit,Guizhou,Southwest China     

朱笑青  王中刚 《中国地球化学学报》2002,21(4):370-373

The mode of occurrence of gold in the Yata micro-disseminated gold deposit is ap-proached through chemical phase studies coupled with ore-dressing monitoring and micro-beam analysis.The results showed that gold occurred for the most part as ultra-microscopic particles adsorbed on the surfaces or fracture planes of pyrite and other sulphides.The proportions of gold of different occurrences were estimated solutions containing nanometer-sized gold particles were prepared following the hydrolysis-reduction procedure and the adsorption of nanometer-sized gold on ordinary sulphides and rocks was experimentally determined.It is evident that sulphides are good adsorbents of gold and this is consistent with geological observations.  相似文献   

REE Geochemistry of the Lead—Zinc Ores from the Jinding Lead—Zinc Deposit,Lanping,Yunnan   总被引：3，自引：1，他引：3  

牟传龙  余谦  张立生 《中国地球化学学报》2002,21(1):57-64

Nineteen volcanic and magmatic rock samples were collectecd from the Jinding leadzinc deposit and its surrounding areas in Yunnan.The ICP and AES analyses,feferred to the previous results,show that the metal minerals and altered rocks in the Jinding lead-zinc deposit display a decreasing trend of ∑REE from the early to late stages of mineralization,and similarities in REE distribution patterns,indicating that the ore fluids are characterized by high LREE enrichment,markedly negative δCe anomaly and slight δEu anomaly.These REE distribution paterns exhibit striking similarities to those of the Pliocene trachyte in the study area,both of which are similar in ∑REE,LREE/HREE ratio,δEu and δCe.The ore fluids besides the basin fluids in the deposit are also closely related to those associated with Pliocene trachyte magmas.  相似文献   

Rare earth elements in waters from the albitite-bearing granodiorites of Central Sardinia, Italy   总被引：1，自引：0，他引：1  

Riccardo BiddauRosa Cidu  Franco Frau 《Chemical Geology》2002,182(1):1-14

With the aim of contributing to the knowledge of the geochemical behaviour and mobility of the rare earth element (REE) in the natural water systems, the ground and surface waters of the Ottana-Orani area (Central Sardinia, Italy) were sampled. The study area consists of albititic bodies included in Hercynian granodiorites. The waters have pH in the range of 6.0-8.6, total dissolved solid (TDS) of between 0.1 and 0.6 g/l, and major cation composition dominated by Ca and Na, whereas predominant anions are Cl and/or HCO₃.The pH and the major-element composition of the waters are the factors affecting the concentration of REE in solution. The concentrations of ∑REE+Y in the samples filtered at 0.4 μm vary between 140 and 1600 ng/l, with La of between 14 and 314 ng/l, and Yb of between <6 and 12 ng/l. A negative Ce anomaly, especially marked at high pH, is observed in the groundwaters. The surface waters show lower REE concentrations, which are independent of pH, and negligible Ce anomaly.Speciation calculations, carried out with the EQ3NR computer program, showed that the complexes with the CO₃²⁻ ligand are the dominant REE species at pH in the range of 6.7-8.6. The REE³⁺ ions dominate the speciation at pH <6.7 and only in the light REE (LREE).The relative concentrations of REE in water roughly reflect those in the aquifer host rocks. However, when concentrations of REE in water are normalised relative to the parent rocks, a preferential fractionation of heavy REE (HREE) into the water phase can be observed, suggesting the greater mobility and stability of HREE in aqueous solution.  相似文献   

玛曲县格尔柯金矿床控矿地质条件及其矿床成因探讨   总被引：3，自引：0，他引：3       下载免费PDF全文

李真善  谢建强  李文军 《甘肃地质》2002,11(1):50-58

格尔柯金矿 (即大水金矿 )是产于西秦岭南带西倾山—迭山逆冲褶断带南缘的特大型金矿。矿床控矿地质条件为构造单元界断裂带、深源浅成花岗闪长斑岩小侵入体、下三叠统马热松多组 (T1m)碳酸盐岩沉积建造 ,与金矿关系密切的矿化蚀变有硅化、赤铁矿化、褐铁矿化和方解石化 ;矿床成因类型为层控—热水溶滤构造蚀变岩型。  相似文献   

甘肃小柳沟钨多金属矿地质特征及成矿模式   总被引：12，自引：1，他引：12       下载免费PDF全文

安涛  周继强 《甘肃地质》2002,11(2):54-66

小柳沟钨多金属矿于 90年代初发现 ,目前已具大型、超大型规模。共有 4个矿床。成矿主要与长城系朱龙关群和隐伏花岗岩有关。该矿床成矿物质来源具双重性 ,成矿温度为中高温 ,成矿流体为中等盐度 ,同位素计算模式年龄确定其成矿于加里东期。矿床成因属于火山喷发沉积—岩浆热液改造矿床。  相似文献   

中条山西南段与变基性岩有关的铜矿地质特征及成因浅析     

薛克勤  赵月凤  董清雷 《华北地质》2002,(Z1)

与变基性岩有关的铜矿 ,是在中条山西南段新发现的一种新的铜矿类型 ,其形成是在原始基性岩浆侵入或喷发作用形成的矿源岩或矿化体基础上 ,经过区域变质和印支 -燕山期构造 -岩浆热液的改造加富而成 ,其成因应属与变基性岩有关的变质 -热液改造型铜 (镍、铁 )矿床。  相似文献